Quantum Harmonic Oscillator: Schrodinger Equation
The Schrodinger equation with this form of potential is
Since the derivative of the wavefunction must give back the square of x plus a constant times the original function, the following form is suggested:
Note that this form (a Gaussian function) satisfies the requirement of going to zero at infinity, making it possible to normalize the wavefunction.
Substituting this function into the Schrodinger equation and fitting the boundary conditions leads to the ground state energy for the quantum harmonic oscillator:
While this process shows that this energy satisfies the Schrodinger equation, it does not demonstrate that it is the lowest energy. One interesting way to show that is to demonstrate that that it is the lowest energy allowed by the uncertainty principle.
The wavefunctions for the quantum harmonic oscillator contain the Gaussian form which allows them to satisfy the necessary boundary conditions at infinity. In the wavefunction associated with a given value of the quantum number n, the Gaussian is multiplied by a polynomial of order n called a Hermite polynomial. The expressions are simplified by making the substitution
The general formula for the normalized wavefunctions is
The quantum harmonic oscillator is one of the foundation problems of quantum mechanics. It can be applied rather directly to the explanation of the vibration spectra of diatomic molecules, but has implications far beyond such simple systems. It is the foundation for the understanding of complex modes of vibration in larger molecules, the motion of atoms in a solid lattice, the theory of heat capacity, etc. In real systems, energy spacings are equal only for the lowest levels where the potential is a good approximation of the "mass on a spring" type harmonic potential. The anharmonic terms which appear in the potential for a diatomic molecule are useful for mapping the detailed potential of such systems.
Schrodinger equation concepts